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(1) Temperature : The surface tension of liquid decreases with rise of temperature. The surface tension of liquid is zero at its boiling point and it vanishes at critical temperature. At critical temperature, intermolecular forces for liquid and gases becomes equal and liquid can expand without any restriction. For small temperature differences, the variation in surface tension with temperature is linear and is given by the relation \[{{T}_{t}}={{T}_{0}}(1-\alpha \,t)\] where \[{{T}_{t}}\], \[{{T}_{0}}\] are the surface tensions at \[{{t}^{o}}C\] and \[{{0}^{o}}C\] respectively and a is the temperature coefficient of surface tension. Examples : (i) Hot soup tastes better than the cold soup. (ii) Machinery parts get jammed in winter. (2) Impurities : The presence of impurities either on the liquid surface or dissolved in it, considerably affect the surface tension, depending upon the degree of contamination. A highly soluble substance like sodium chloride when dissolved in water, increases the surface tension of water. But the sparingly soluble substances like phenol when dissolved in water, decreases the surface tension of water.  

 
(1) When mercury is split on a clean glass plate, it forms globules. Tiny globules are spherical on the account of surface tension because force of gravity is negligible. The bigger globules get flattened from the middle but have round shape near the edges.         (2) When a greased iron needle is placed gently on the surface of water at rest, so that it does not prick the water surface, the needle floats on the surface of water despite it being heavier because the weight of needle is balanced by the vertical components of the forces of surface tension. If the water surface is pricked by one end of the needle, the needle sinks down.
(3) When a molten metal is poured into water from a suitable height, the falling stream of metal breaks up and the detached portion of the liquid in small quantity acquire the spherical shape.           (4) Take a frame of wire and dip it in soap solution and take it out, a soap film will be formed in the frame. Place a loop of wet thread gently on the film. It will remain in the form, we place it on the film according to figure. Now, piercing the film with a pin at any point inside the loop, It immediately takes the circular form as shown in figure.  
(5) Hair of shaving brush/painting brush when dipped in water spread out, but as soon as it is taken out, its hair stick together. (6) If a small irregular piece of camphor is floated on the surface of pure water, it does not remain steady but dances about on the surface. This is because, irregular shaped camphor dissolves unequally and decreases the surface tension of the water locally. The unbalanced forces make it to move haphazardly in different directions.
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If a body of weight W is placed on the liquid surface, whose surface tension is T. If F is the minimum force required to pull it away from the water then value of F for different bodies can be calculated by the following table.      
Body Figure Force
Needle (Length \[=l\]) \[F=2lTW\]
Hollow disc (Inner radius \[={{r}_{1}}\] Outer radius \[={{r}_{2}}\]) \[F=2\pi ({{r}_{1}}+{{r}_{2}})T+W\]
Thin ring (Radius \[=r\]) \[F=2\pi (r+r)T+W\] \[F=4\pi rT+W\]
Circular plate or disc (Radius \[=r\]) \[F=2\pi rT+W\]
Square frame (Side = l ) more...
The property of a liquid due to which its free surface tries to have minimum surface area and behaves as if it were under tension somewhat like a stretched elastic membrane is called surface tension. A small liquid drop has spherical shape, as due to surface tension the liquid surface tries to have minimum surface area and for a given volume, the sphere has minimum surface area. Surface tension of a liquid is measured by the force acting per unit length on either side of an imaginary line drawn on the free surface of liquid, the direction of this force being perpendicular to the line and tangential to the free surface of liquid. So if F is the force acting on one side of imaginary line of length L, then T = (F/L) (1) It depends only on the nature of liquid and is independent of the area of surface or length of line considered. (2) It is a scalar as it has a unique direction which is not to be specified. (3) Dimension : \[[M{{T}^{-2}}]\].         (Similar to force constant) (4) Units : N/m (S.I.) and Dyne/cm [C.G.S.] (5) It is a molecular phenomenon and its root cause is the electromagnetic forces.  

The force of attraction or repulsion acting between the molecules are known as intermolecular force. The nature of intermolecular force is electromagnetic. The intermolecular forces of attraction may be classified into two types.
Cohesive force Adhesive force
The force of attraction between molecules of same substance is called the force of cohesion. This force is lesser in liquids and least in gases. The force of attraction between the molecules of the different substances is called the force of adhesion.  
Ex. (i) Two drops of a liquid coalesce into one when brought in mutual contact. (ii) It is difficult to separate two sticky plates of glass welded with water. (iii) It is difficult to break a drop of mercury into small droplets because of large cohesive force between the mercury molecules. Ex. (i) Adhesive force enables us to write on the blackboard with a chalk. (ii) A piece of paper sticks to another due to large force of adhesion between the paper and gum molecules. (iii) Water wets the glass surface due to force of adhesion.
  Note :
  • Cohesive or adhesive forces are inversely proportional to the eighth power of distance between the molecules.  

(i) The metallic parts of machinery are never subjected to a stress beyond elastic limit, otherwise they will get permanently deformed. (ii) The thickness of the metallic rope used in the crane in order to lift a given load is decided from the knowledge of elastic limit of the material of the rope and the factor of safety. (iii) The bridges are declared unsafe after long use because during its long use, a bridge under goes quick alternating strains continuously. It results in the loss of elastic strength. (iv) Maximum height of a mountain on earth can be estimated from the elastic behaviour of earth. At the base of the mountain, the pressure is given by P = hrg and it must be less than elastic limit (K) of earth?s supporting material. \[K>P>h\rho g\] \[\therefore \] \[h<\frac{K}{\rho g}\] or \[{{h}_{\max }}=\frac{K}{\rho g}\] (v) In designing a beam for its use to support a load (in construction of roofs and bridges), it is advantageous to increase its depth rather than the breadth of the beam because the depression in rectangular beam.   \[\delta =\frac{W{{l}^{3}}}{4Yb{{d}^{3}}}\]     To minimize the depression in the beam, it is designed as I-shaped girder. (vi) For a beam with circular cross-section depression is given by \[\delta =\frac{W{{L}^{3}}}{12\pi \,{{r}^{4}}Y}\] (vii) A hollow shaft is stronger than a solid shaft made of same mass, length and material. Torque required to produce a unit twist in a solid shaft \[{{\tau }_{\text{solid}}}=\frac{\pi \eta {{r}^{4}}}{2l}\]                                            ...(i) and torque required to produce a unit twist in a hollow shaft \[{{\tau }_{\text{hollow}}}=\frac{\pi \eta (r_{2}^{4}-r_{1}^{4})}{2l}\]                      ...(ii) From (i) and (ii), \[\frac{{{\tau }_{\text{hollow}}}}{{{\tau }_{\text{solid}}}}=\frac{r_{2}^{4}-r_{1}^{4}}{{{r}^{4}}}=\frac{(r_{2}^{2}+r_{1}^{2})(r_{2}^{2}-r_{1}^{2})}{{{r}^{4}}}\]            ...(iii) Since two shafts are made from equal volume \[\therefore \] \[\pi {{r}^{2}}l=\pi (r_{2}^{2}-r_{1}^{2})l\]\[\Rightarrow \] \[{{r}^{2}}=r_{2}^{2}-r_{1}^{2}\] Substituting this value in equation (iii) we get, \[\frac{{{\tau }_{\text{hollow}}}}{{{\tau }_{\text{solid}}}}=\frac{r_{2}^{2}+r_{1}^{2}}{{{r}^{2}}}>1\]  \[\therefore \] \[{{\tau }_{\text{hollow}}}>{{\tau }_{\text{solid}}}\] i.e., the torque required to twist a hollow shaft is greater than the torque necessary to twist a solid shaft of the same mass, length and material through the same angle. Hence, a hollow shaft is stronger than a solid shaft.

(1) The body which requires greater deforming force to produce a certain change in dimension is more elastic. Example : Ivory and steel balls are more elastic than rubber. (2) When equal deforming force is applied on different bodies then the body which shows less deformation is more elastic. Example : (i) For same load, more elongation is produced in rubber wire than in steel wire hence steel is more elastic than rubber. (ii) Water is more elastic than air as volume change in water is less for same applied pressure. (iii) Four identical balls of different materials are dropped from the same height then after collision, balls rises upto different heights. The order of their height can be given by \[{{h}_{ivory}}>{{h}_{steel}}>{{h}_{rubber}}>{{h}_{clay}}\] because \[{{Y}_{ivory}}>{{Y}_{steel}}>{{Y}_{rubber}}>{{Y}_{clay}}\]. (3) The value of moduli of elasticity is independent of the magnitude of the stress and strain. It depends only on the nature of material of the body. (4) For a given material there can be different moduli of elasticity depending on the type of stress applied and resulting strain.  
Name of substance Young?s modulus (Y) \[{{10}^{10}}N/{{m}^{2}}\] Bulk modulus (K) \[{{10}^{10}}N/{{m}^{2}}\] Modulus of rigidity \[(\eta )\]\[{{10}^{10}}N/{{m}^{2}}\]
Aluminium 6.9 7.0 2.6
Brass 9.0 6.7 more...
(1) Hammering and rolling : Crystal grains break up into smaller units by hammering and rolling. This results in increase in the elasticity of material. (2) Annealing : The metals are annealed by heating and then cooling them slowly. Annealing results in decrease in the elasticity of material. (3) Temperature : Intermolecular forces decreases with rise in temperature. Hence the elasticity decreases with rise in temperature but the elasticity of invar steel (alloy) does not change with change of temperature. (4) Impurities : Due to impurities in a material, elasticity can  increase or decrease. The type of effect depends upon the nature of impurities present in the material.  

When a deforming force is applied on a body then the strain does not change simultaneously with stress rather it lags behind the stress. The lagging of strain behind the stress is defined as elastic hysteresis. This is the reason why the values of strain for same stress are different while increasing the load and while decreasing the load. Hysteresis loop : The area of the stress-strain curve is called the hysteresis loop and it is numerically equal to the work done in loading the material and then unloading it. If we have two tyres of rubber having different hysteresis loop then rubber B should be used for making the car tyres. It is because of the reason that area under the curve i.e. work done in case of rubber B is lesser and hence the car tyre will not get excessively heated and rubber A should be used to absorb vibration of the machinery because of the large area of the curve, a large amount of vibrational energy can be dissipated.  

Behaviour of solids with respect to external forces is such that if their atoms are connected to springs. When an external force is applied on a solid, this distance between its atoms changes and interatomic force works to restore the original dimension. The ratio of interatomic force to that of change in interatomic distance is defined as the interatomic force constant. \[K=\frac{F}{\Delta r}\] It is also given by \[K=Y\times {{r}_{0}}\] [Where \[Y\]= Young's modulus, \[{{r}_{0}}=\] Normal distance between the atoms of wire] Unit of interatomic force constant is N/m and Dimension \[M{{T}^{-2}}\] Note :
  • The number of atoms having interatomic distance \[{{r}_{0}}\] in length \[l\] of a wire, \[N=l/{{r}_{0}}\].
The number of atoms in area A of wire having interatomic separation \[{{r}_{0}}\] is \[N=A/r_{0}^{2}\].  


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