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  Metals and Non-metals ²
  • Metals and Non-metals: There are more than 114 elements present in the periodic table. These elements can be broadly classified into two categories i.e., metals and non-metals. Out of 114 elements, 22 are non-metals.
  • Physical properties of metals:
(i) They are usually shiny i.e. have a metallic luster. (ii) Metals have a high density (iii) Metals are ductile i.e. they can be drawn into wires. (iv) Metals are malleable i.e. they can be founded into thin sheets. (v) Metals are good conductors of electricity. (vi) Metals have high melting point and are generally in solid state at room temperature. (vii) Metals are good conductors of heat and sound.
  • Uses of metals:
(i) Metals are very important for modern humans it is not possible to imagine our life without them. (ii) Metals are used in manufacturing of bridges, railways, aeroplanes, diesel mobile units (DMU), electric mobile units (EMU), motor cars, electric motors, telephones, televisions, interplanetary space vehicles, or even common articles like cooking utensils and coins. (iii) Metals are very important for the economy of a country. Some metals, such as titanium, chromium, manganese and zirconium are strategic metals. These metals and their alloys find wide applications in atomic energy, space science projects, jet engines and high grade steels. (iv) Gold and silver ornaments are obtained from small pieces of metals by hammering.
  • Noble metal: Noble metals are metals that are resistant to corrosion or oxidation, unlike most base metals. Examples include tantalum, gold, platinum, and rhodium.
  • Precious metal: A precious metal is a rare metallic chemical element of high economic value precious metals include the platinum group metals: ruthenium, rhodium, palladium, osmium, indium, and platinum, of which platinum is the most widely traded.
  • Alloy: An alloy is a mixture of two or more elements in solid solution in which the major component is a metal. Most pure metals are either too soft, brittle or chemically reactive for practical use. Combining different ratios of metals as alloys modify the properties of pure metals to produce desirable characteristics. The aim of making alloys is generally to make them less brittle, harder, resistant to corrosion, or have a more desirable color and luster. Examples of alloys are steel (iron and carbon), brass (copper and zinc), bronze (copper and tin), and duralumin (aluminium and copper).
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  Introduction  
  • The pollutants may be inorganic, biological or radiological in nature.
(i) Bio-degradable pollutants are domestic wastes which are rapidly decomposed by micro-organisms. (ii) Non-biodegradable pollutants include chemicals, mercuric salts, lead compounds, pesticides, etc. (iii) Natural pollution is caused by radioactive substances, volcanic eruptions, forests and mines fires floods, etc. (iv) Artificial pollution is caused by industries, thermal plants, automobile, exhausts, sewage, etc.   Environment  
  • Environment: The conditions existing around animal or human life.
Atmosphere: The gaseous envelop surrounding the earth. It has been classified into following regions:- (i) Stratosphere: The layer of the earth's atmosphere above the troposphere and below the mesosphere. (ii) Troposphere: The lowest region of the atmosphere extending from earth's surface to the lower boundary of the stratosphere. In this region, human beings along with other organisms live. It contains water vapour and is greatly affected by air pollution. Note: The other two layers are Thermosphere and Mesosphere.   Air pollution  
  • Air pollution: The major air pollutants are
(i) Carbon monoxide (CO): It is produced by incomplete combustion of gasoline in motor vehicles, wood, coal, inceneration and forest fires. It is treacherous and deadly poisonous gas. It induces headache, visual difficulty coma and death. It blocks the normal transport of oxygen from the lungs to other parts of the body. (ii) Sulphur dioxide\[(S{{O}_{2}})\]: It is produced by petrol combustion, coal combustion, and petrol refining and smelting operations. It hinders the movement of air in and out of lungs. It is particularly poisonous to trees causing chlorosis and dwarfing. In presence of air it is oxidised to \[S{{O}_{3}}\] which is also irritant.             \[2S{{O}_{2}}+{{O}_{2}}(air)\to 2S{{O}_{3}}\] In presence of moisture \[S{{O}_{3}}\] is converted into highly corrosive sulphuric acid.             \[S{{O}_{3}}+{{H}_{2}}O(moisture)\to {{H}_{2}}S{{O}_{4}}\] It attacks marble, limestone, vegetation, paper and textiles and injurious to human beings. (iii) Oxides of nitrogen: \[N{{O}_{2}}\] and NO, Source - combustion of coal, gasoline, natural gas, petroleum refining, chemical plants, manufacturing explosives and fertilizers, tobacco smoke. Breathing \[N{{O}_{2}}\] causes chlorosis to plants and chronic lung conditions leading to death. \[N{{O}_{2}}\] reacts with moisture to form acids.             \[2N{{O}_{2}}+{{H}_{2}}O\to HN{{O}_{2}}+HN{{O}_{3}}\],             \[3HN{{O}_{2}}\to 2NO+HN{{O}_{3}}+{{H}_{2}}O\] (iv) Smoke, dust: Sources: cement works, iron and steel works, gas works, power generating stations. Smog: It is a mixture of smoke and fog in suspended droplet form. It is of two types:
  • London smog or classical smog: It is coal smoke plus fog. The fog part is mainly \[S{{O}_{2}}\] and \[S{{O}_{3}}\].It has sulphuric acid aerosol. It causes bronchial irritation and acid rain. It is reducing in nature.
  • Photochemical smog or Los Angeles smog: The oxidised hydrocarbons and ozone in presence of humidity cause photochemical smog. Hydrocarbons \[+{{O}_{2}}\], \[N{{O}_{2}}\] NO, O, \[{{O}_{3}}\] \[\to \] Peroxides, formaldehyde, peroxyacetylnitrate (PAN), acrolein etc. It is oxidising in nature and causes irritation to eyes, lungs, nose, and asthamatic attack and damage plants.
Acid rain: The oxides of C, N and S present in more...

  Introduction  
  • Definition
Chemistry is a branch of science which deals with study of matter and various changes it undergoes. It deals with the preparation, properties, reactions and structures of chemical elements and compounds. For convenience the study of chemistry is sub-divided into various branches such as: (i) Inorganic chemistry                 (ii) Organic chemistry                   (iii) Physical chemistry                 (iv) Analytical chemistry              (v) Industrial chemistry
  • Valency
During the formation of molecules of compounds, atoms combine in certain fixed proportions. This is because of the fact that different atoms have different combining capacities. The combining capacity of an atom or radical is known as its valency.
  • Ions or radicals
In addition to atoms and molecules, a third type of particles occurs in substances. These particles, called ions, or atoms or group of atoms that carry an electrical charge. An ion is formed when electrons are removed from or added to an atoms or group of atoms. When electrons is/are removed the resulting ion is called a cation or basic radical. A cation is positively charged ion. (e.g\[N{{a}^{+}}\]. When electron is/are added the resulting ion is called an anion or acidic radicals. An anion is negatively charged ion e.g.,\[(C{{l}^{-}},O_{2}^{2-})\]An ion or radical is classified as monovalent, divalent, trivalent or tetravalent when the number of charges over it is 1,2,3 or 4 respectively.
  • Formula of Elements and Compounds
Formula of dements: The molecule of an element is denoted by writing the symbol of the element and, to the right and below it, a number expressing the number of atoms in the molecule. Formula of compound: A molecule of a compound maybe made up of atom of different elements linked up together chemically and in definite proportion by weight.
  • Chemical formula: It is of two types:
(i) Molecular formulae: Chemical formulae that indicate the actual number and type of atoms in a molecule is called molecular formulae. (ii) Empirical formulae: Chemical formulae that indicate only the relative number of atoms of each type in a molecule is called empirical formulae.
  • Equivalent weight
(i) Equivalent weight of element \[=\frac{Atomic\,\,weight\,\,of\,\,element}{Valency\,\,of\,\,element}\] (ii) Eq. wt of an acid/base\[=\frac{Molecular\,\,mass}{Basicity\,\,of\,\,acid/Acidity\,\,of\,\,base}\] (iii) Eq. wt of salts\[=\frac{Formula\,\,mass}{(Valency\,\,of\,\,cation)(No.of\,\,cations)}\]
  • Expression of strength /concentration of Solution
(i) Mass percent = \[\frac{Weight\,\,of\,\,solute(gm)}{Weight\,\,of\,\,solution(gm)}\times 100\] (ii) Normality \[=\frac{numer\,\,of\,\,gram\,\,equivalents\,\,of\,solute}{Volume\,\,of\,solution\,(lit.)}\] (iii) Molarity =\[\frac{Number\,\,of\,\,gram\,\,moles\,\,of\,\,solute}{Volume\,\,of\,\,solution(lit.)}\] (iv) Molality \[=\frac{Gram\,\,moes\,\,of\,\,solute}{weight\,\,of\,\,solent\,(kg)}\] (v) Mole fraction:  Mole fraction of solute \[={{X}_{A}}=\frac{{{n}_{A}}}{{{n}_{A}}+{{n}_{B}}}\]                           Mole fraction of solvent \[={{X}_{B}}=\frac{{{n}_{B}}}{{{n}_{A}}+{{n}_{B}}}\]                                                             \[{{X}_{A}}+{{X}_{B}}=1\]
  • Chemical reaction: The process in which a substance undergoes change to produce new substances with new properties are known as chemical reaction. For example magnesium carbonate when heated produces magnesium oxide and carbon dioxide (i.e. new substances with new properties). A chemical change is generally accompanied by a change of state, change of colour, evolution of a gas or change of temperature etc.
  • Chemical equation: The qualitative representation of a chemical reaction in a more...

  Introduction  
  • Chemistry has helped significantly in meeting human needs by providing chemical fertilizers, improved varieties of insecticides and pesticides to increase the yield of crops and fruits. It has given us a large number of lifesaving drugs. Also chemical industries manufacturing polymers, soaps, detergents, glass, ceramics etc.
  Industrially Important Compounds Glass It consists of a mixture of two or more silicates.
  • Preparation of glass:
  • Common glass (or soft glass): It is used to make bottles, glass wares etc. and is obtained by heating together silica (in the form of sand), sodium carbonate or sodium sulphate and chalk or lime stone (calcium carbonate). Some broken glass and a little coke are usually added. The glass so prepared consists of silicates of sodium and calcium.
\[N{{a}_{2}}C{{O}_{3}}(s)+\underset{\left( silica \right)}{\mathop{Si{{O}_{2}}(s)}}\,\to N{{a}_{2}}Si{{O}_{3}}(s)+C{{O}_{2}}(g)\] \[N{{a}_{2}}S{{O}_{4}}(s)+Si{{O}_{2}}(s)\to N{{a}_{2}}Si{{O}_{3}}(s)+S{{O}_{3}}(g)\] \[CaC{{O}_{3}}(s)+Si{{O}_{2}}(s)\to CaSi{{O}_{3}}(s)+C{{O}_{2}}(g)\]
  • Hard glass: For preparation of hard glass \[{{K}_{2}}C{{O}_{3}}\] is used in place of\[N{{a}_{2}}C{{O}_{3}}\]. It consists of a mixture of calcium and potassium silicates.
  • Physical properties of glass: Hard, rigid, high viscosity, bad conductor of heat and electricity, brittle, etc.
  • Blowing: It is a method to cast the molten glass into different moulds. There are two different methods of glass blowing (i) Free blowing and (ii) Mould blowing
  • Free blowing: It involves the blowing of air to inflate the molten glass which is gathered at one end of the blow pipe to give the desired shape.
  • Mould blowing: This method was developed after' the technique of free blowing. In this method, molten glass is inflated into a wooden or metal carved mould with the help of blow pipe which gives the molten glass the shape and design of the interior of the mould.
  • Chemical properties of glass
(i) It is resistant to action of air and acids except hydroflouric acid. (ii) It is alkaline in nature. (iii) It slowly reacts with water to form alkaline solution.
  • Types of Glass
(i) Silica glass: For this type of glass the raw material used is 100% pure form of quartz. It is quite expensive. It is used in the manufacture of laboratory apparatus. It has low thermal expansion. Its softening point is very high and it is resistant to a wide variety of chemicals. (ii) Alkali silicate glass: For it the raw materials used are sand and soda. It is also called water glass because it is soluble in water and used only as a solution. It is generally used to make gums and adhesives. (iii) Lead glass: For this type of glass lead oxide is added to ordinary glass. The addition of lead oxide increases the density and also the refractive index. This type of glass is used for the manufacture of ornamental glass ware, decorative articles etc. (iv) Optical glass: This type of glass is used in the manufacture of optical instruments like binoculars, spectacles, lenses, prisons, telescopes, microscopes etc. It is transparent and can be more...

General Organic Chemistry  
  • Wohler prepared the first organic compound urea while preparing ammonium cyanate.
  • Classification of organic compounds:
 
  • The existence of two or more chemical compounds with the same molecular formula but having different properties owing to different arrangement of atoms within the molecule is termed as isomerism
   
  • Hydrocarbons: All those compounds which contain just carbon and hydrogen are called hydrocarbons.
  • Functional group: The atom or group of atoms which determine the properties of a compound is known as functional group. e.g. \[-OH\] (alcohol), -CHO (aldehyde), > C = C < (alkene), \[-C\equiv C-\] (alkyne), etc.
  • Homologous Series: A series of compounds in which the same functional group substitute’s hydrogen in a carbon chain is called a homologous series, e.g. \[C{{H}_{3}}Cl\] .and \[{{C}_{2}}{{H}_{5}}Cl\] differ by a \[-C{{H}_{2}}\] unit.
  • Nomenclature: Chemists developed a set of rules, for naming organic compounds based on their structures which is known as IUPAC rules. The IUPAC name of an organic compounds consists of three parts.
Prefix - word root - Suffix Word root: A word root indicates the nature of basic carbon skeleton.
  • In case a functional group is present, it is indicated in the name of the compound with either as a prefix or as suffix.
  • While adding the suffix to the word root the terminal 'e' of carbon chain is removed
  • If the carbon chain is unsaturated then the final 'ane' in the name of the carbon chain is substituted by 'ene' or ‘yne’ respectively for double and triple bonds.
 
Alloy Composition Uses
1. Brass Cu = 80%, Zn = 20% For making utensils and cartridges.
2. Bronze Cu = 90%, Sn = 10% For making statues, medals, ships, coins and machines
3. Solder Sn = 50%, Pb = 50% For joining metals, solding wire and electronic components etc.
Functional group Prefix/Suffix Functional group Example IUPAC Name
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  Introduction  
  • Biodiversity refers number and types of wide variety of plants and animals present on earth.
  • In 1773, Swedish botanist Carolus Linnaeus formulated the system of Binomial Nomenclature in his book 'Species plantarum''. In binomial system, each name is expressed in two parts i.e., generic name and specific name.
  • Taxon is the branch of biology that deals with the framing of laws and principles for classifying the organisms on the basis of their characteristics and evolutionary relationships.
  • The hierarchial system of classification was introduced by
Kingdom \[\to \] Phylum or Division\[\to \] Class\[\to \] Order\[\to \]Family\[\to \] Genus\[\to \]Species
  • Species is defined as "the smallest real basic unit of taxonomy which is reproductively isolated from other group of individuals".
  • Genus is a group of closely related species that are alike in broad features of their organization.
  • Family is a group of related genera having several common characters.
  • Generally, Order and other higher taxonomic categories are identified based on the aggregates of characters.
  • A Class is made of one or more related orders.
  • The term Phylum is used for animals while Division is commonly employed for plants.
  • Kingdom is the highest taxonomic category. All plants are included in Kingdom Plantae. All animals are included in Kingdom Animalia.
  • Herbarium is a collection of pressed and dried plant specimens that are preserved on paper sheets.
  • In Botanical garden, various plants groups are grown for scientific study, conservation, public education, aesthetics, and recreation. The famous botanical gardens are at Kew (England), Indian Botanical Garden, Howrah (India) and
  • National Botanical Research Institute, Lucknow (India).
  • Museum is a building used for the preservation, storage and exhibition of inanimate objects.
  • Zoological park or zoological garden or zoo is a place where wild animals are kept in protected environment under human care. These animals are kept for public exhibition.
² History of Classification
  • Biological classification was first proposed by Aristotle who used simple morphological characters to classify plants and animals.
  • Linnaeus initially separated plants and animals in two Kingdoms i.e., Kingdom Plantae and Kingdom Animalia.
  • Most accepted System of classification is five system classification which was given by Whittaker.
 
  • Basic Feature of Whittaker’s Five Kingdoms
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  Introduction  
  • Cell is a basic structural and functional unit of life.
  • Robert Hooke in 1665 coined the word 'cell'.
  • Anton von Leeuwenhoek first saw and described a live cell.
  • Robert Brown later had discovered the nucleus.
  • Cell theory was proposed by Schleiden and Schwann in 1855 to explain the concept of the cellular nature of living organism.
 
  • Prokcaryotic Cells
  • Prokaryotic cells are morphologically most primitive.
  • Prokaryotic cells are devoid of membrane bound organelles like plastids, mitochondria and advanced (9+2) flagella.
  • Prokaryotic cells are represented by bacteria, cyanobacteria (blue green algae) mycoplasma and PPLO (pleuropneumonia like organisms).
 
  • Eukaryotic Cells:
A eukaryotic cell consists of the following components:  
  • Cell Wall
  • The cell wall is a non-living, semi-rigid, external protective covering of the cell.
  • Cell wall is entirely lacking in animals.
  • It is made up of cellulose secreted by the cell itself.
 
  • Cell Mebrane
  • The cell membrane is a living, thin, elastic and semi- permeable membranous covering of plant and animal cells.
 
  • Fluid mosaic model of plasma membrane
  • J. Singer and G. Nicolson in 1972 proposed the most accepted model of membrane structure. The plasma membrane is a lipid-bilayer with proteins embedded in it.
  • Lipids are amphipathic, i.e., they are structurally asymmetric with polar hydrophilic and non-polar hydrophobic group.
  • One of the most important function of plasma membrane is the transport of the molecules across it.
 
  • Endoplasmic Reticulum (ER)
There are two types of endoplasmic reticulum i.e.,
  • Smooth or agranular ER - They do not have attached ribosomes on their surface.
  • Rough or granular ER - They bear ribosomes on their surface, for protein synthesis.
 
  • Golgi apparatus
  • Golgi apparatus or Golgi complex is a stack of flattened, membrane bounded, parallely arranged organelles that occur in the association of endoplasmic reticulum in the cytoplasmic matrix.
  • The Golgi apparatus principally performs the function of packaging materials to be delivered either to the intra-cellular targets or secreted outside the cell.
 
  • Lysosomes
  • Lysosomes are popularly called "suicide bags".
 
  • Vacuoles
  • In plant cells, the vacuoles can occupy up to 90 percent of the volume of the cell. The vacuole is bound by a single membrane called tonoplast. They are responsible for maintenance of turgour pressure.
 
  • Mitochondria
  • Mitochondria are also called as powerhouse of cells.
 
  • Plastids
  • Plastids are found in plants and few protists Euglena.
 
  • Ribosomes
  • Ribosomes are smallest cell organelles. They are protein synthesising factories. There are two types of ribosomes viz., Prokaryotic or 70S ribosomes - Eukaryotic or 80S ribosomes
  Nucleus  
  • Nucleus is centrally located, spherical and largest more...

  Means of Transport  
  • Diffusion is a random movement of individual molecules from a region of higher concentration to a region of lower concentration. Diffusion rates are affected by concentration gradient, membrane permeability, temperature and pressure.
  • The substance that have a hydrophilic moiety, find it difficult to pass through membrane. The movement of such molecules are facilitate, for which proteins provide site at which such molecule cross membrane. This is called as facilitated diffusion.
  • Active transport uses energy to pump molecules against a concentration gradient.
  Plants-Water Relations  
  • Water Potential: The potential energy of water is referred to as water potential. It is measured in term of pressure.
\[{{\psi }_{w}}={{\psi }_{s}}+{{\psi }_{p}}\]
  • Osmosis: It is the diffusion of water through a semi-permeable membrane. It depends on two factors
(i) Concentration of dissolved solutes in a solution (ii) Pressure difference.
  • Plasmolysis: If a turgid cell is placed in a solution that has more solutes, it exerts a higher osmotic pressure and water will move out.
  • Isotonic solution: When concentration of outer solution (in which cell is placed) is equal to concentration of cell sap.
  • Hypotonic solution: When concentration of outer solution is lower than concentration of cell sap.
  • Hypertonic solution: When concentration of outer solution is higher than concentration of cell sap.
 
  • Imbibition: It is a type of diffusion by which movement of water takes place along a diffusion gradient. Factors influencing the rate of imbibition are nature of imbibant, surface area of imbibant, temperature, concentration of solutes, pH of imbibant.
 
  • Cohesion Theory:
  • Proposed by Henry Dixon 1914.
  • Evaporation of water from the leaf to atmosphere decreases the water potential of the epidermal cells.
 
  • Transpiration
  • Loss of water in the form of water vapour from plant through the small pores (stomata) present on leaves is called transpiration.
 
  • The Pressure Flow or Mass Flow Hypothesis
  • It was put forward by Munch (1930). According to this hypothesis, organic substances move from the region of high osmotic pressure to the region of low osmotic pressure in a mass flow due to the development of a gradient of turgor pressure.
  • Hydroponics: The system of growing plants in soilless culture (also called solution culture or tank farming) is known as hydroponics.
  Role of Essential Elements (Macro and Micro) and their Deficiency Symptoms           
  Kingdom Cellular Organization Movement
S. No. Name of element In which form they are absorbed more...
  Introduction  
  • The food that we consume must be broken down into simpler absorbable forms so that they can be easily absorbed and transported to various parts of our body through blood. This task is accomplished by the digestive system.
 
  • Dental formula for adult human
\[\frac{Upper\,\,jaw}{Lower\,\,jaw}=\frac{IC\,PmM}{IC\,PmM}=\frac{2123}{2123}\]  
  • Digestion of Food
Name of the Digestive Name of the enzymes Substrate End product
Saliva Ptyalin (Salivary amylase) Starch Maltose
Pancreatic iuice Amylopsin (pancreatic amylase) Starch, Glycogen Maltose and Glucose
Intestinal juice Sucrase (invertase), Maltase, Lactase Sucrose; Maltose, Lactose Glucose and fructose. Glucose, Glucose and galactose
Gastric iuice Pepsin, Rennin more...
  Introduction  
  • Study of heredity and variation is called genetics.
  • Term genetics was given by - Bateson.
  • Father of genetics - Gregor Johann Mendel.
  • Father of experimental genetics - Thomas Hunt Morgan.
  • Father of human genetics - Archibald Garrod.
 
  • Some Terms in Genetics
  • Gene: It is segment of DNA. It is basic unit of heredity
  • Back cross: It is cross which is performed between hybrid and one of its parents.
  • Test cross: Test cross is crossing of offspring with unknown dominant phenotype with the individual homozygous recessive for the trait.
  • Monohybrid cross: It is a cross between two organisms of a species which is made to study the inheritance of a single pair of alleles or factors of a character.
  • Monohybrid ratio: Monohybrid ratio is usually 3:1 (phenotypic ratio) or 1: 2:1 (genotype ratio) in which 25% of the individuals carry the recessive trait, 25% pure dominant and 50% have hybrid dominant trait.
  • Dihybrid cross: It is a cross between two organisms of a species which is made to study the inheritance of two pairs of factors or alleles of two genes.
  • Dihybrid ratio: Dihybrid ratio is 9: 3: 3: 1 (phenotypic ratio) where 9/16 first recessive and second dominant and 1/16 carry both the recessive traits.
  • Mendel conducted cross hybridization experiments on Garden Pea plant (Pisum sativum). The first was the Principle of segregation, which claimed that each trait was specified by paired hereditary determinants (alleles of genes) that separate from each other during gamete formation. This law is also called Law of purity of gametes or Law of splitting of hybrids.
  • Gregor Mendel was the first individual to apply a modem scientific approach to the study of heredity. Mendel proposed two basic principles of trasmission genetics.
  • Mendel's second basic conclusion was the Principle of independent assortment, which stated that the segregation of one pair of genes-controlling a given trait - was not influenced by the segregation of other gene pairs. The chormosome theory provided a physical basis for the principle of independent assortment. Genes located on different chromosomes move to gametes independently of each other during meiosis.
 
  • Human Blood Groups and Multiple Allele
  • The system of blood groups in humans was discovered by Karl Landsteiner in 1900s.
  • There are four phenotypes of Blood namely A, B, AB and O produced by three different alleles.\[{{I}^{A}}\],\[{{I}^{B}}\]and i of a gene.
  • The allele\[{{I}^{A}}\] and \[{{I}^{B}}\] are equally dominant and do not interfere with expression of each other hence the allele \[{{I}^{A}}{{I}^{B}}\] are said to be co-dominant because both are expressed in the phenotype AB.
  • Linkage is the phenomenon of certain genes staying together during inheritance through generations without any change or separation due to their being present on the same chromosomes.
  • Linkage in the genes can be identified by test cross.
  • The rearrangements of linked genes due to crossing over is known as recombination. Recombination also occurs more...


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