J & K CET Engineering J and K - CET Engineering Solved Paper-2014

  • question_answer
    Based on which method amines are prepared?

    A)  Reduction of nitro compounds

    B)  Ammonolysis of alkyl halides

    C)  Reduction of nitrites and amides

    D)  All of the above

    Correct Answer: D

    Solution :

     Amine may be prepared from following methods [a] From reduction of nitro compounds \[RN{{O}_{2}}+3{{H}_{2}}\xrightarrow{Ni/250{{\,}^{o}}C}RN{{H}_{2}}+2{{H}_{2}}O\] [b] From Hofmann's ammonolysis method \[Rl\xrightarrow[-HI]{N{{H}_{3}}/393K}RN{{H}_{2}}\] [c] From reduction of nitriles and amides \[RC\equiv N\xrightarrow{LiAl{{H}_{4}}}RC{{H}_{2}}N{{H}_{2}}\] \[RCON{{H}_{2}}\xrightarrow{LiAl{{H}_{4}}}RC{{H}_{2}}N{{H}_{2}}\]


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