A) \[C{{H}_{3}}C{{H}_{2}}C{{H}_{2}}I\]
B) \[C{{H}_{3}}-\underset{\text{I}}{\mathop{\underset{|}{\mathop{CH}}\,}}\,-C{{H}_{3}}\]
C) \[\underset{\text{I}}{\mathop{\underset{|}{\mathop{C}}\,}}\,{{H}_{2}}-CH=C{{H}_{2}}\]
D) \[\underset{\text{I}}{\mathop{\underset{|}{\mathop{C}}\,}}\,{{H}_{2}}-\underset{\text{I}}{\mathop{\underset{|}{\mathop{C}}\,}}\,{{H}_{2}}\]
Correct Answer: B
Solution :
The product of given reaction will be according to Markownik of Ps rule, this is because peroxide effect is applicable only in case of HBr and not effective in case of HI. \[C{{H}_{3}}-CH=C{{H}_{2}}\xrightarrow[peroxide]{HI}C{{H}_{3}}-\underset{\text{I}}{\mathop{\underset{|}{\mathop{CH}}\,}}\,-C{{H}_{3}}\]
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