VMMC VMMC Medical Solved Paper-2013

  • question_answer
    The octahedral complex ion \[{{[FeC{{l}_{6}}]}^{3-}}\]

    A)  5 unpaired electrons \[(t_{2g}^{3}e_{g}^{2})\]

    B)  1 unpaired electron \[(t_{2g}^{1})\]

    C)  3 unpaired electrons \[(t_{2g}^{1}e_{g}^{2})\]

    D)  All the electrons are paired

    Correct Answer: A

    Solution :

     In \[{{[FeC{{l}_{6}}]}^{3-}},Fe\]is in + 3 oxidation state. Cl is a weak field ligand so the electrons remain unpaired. \[_{26}Fe=[Ar]3{{d}^{6}}4{{s}^{2}};F{{e}^{3+}}=[Ar]3{{d}^{5}}\]  (\[5{{e}^{-}},\]unpaired electrons) Therefore, option \[(a)t_{2g}^{3}e_{g}^{2}\]is correct.


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