VMMC VMMC Medical Solved Paper-2011

  • question_answer
    the electrochemical reaction, \[2F{{e}^{3+}}+Zn\xrightarrow{{}}Z{{n}^{2+}}+2F{{e}^{2+}}\] increasing the concentration of\[\text{F}{{\text{e}}^{\text{2+}}}\]

    A) increases cell emf

    B) increases the current flow

    C)  decreases the cell emf

    D)  alter the pH of the solution

    Correct Answer: C

    Solution :

    \[2F{{e}^{3+}}+Zn\xrightarrow{{}}Z{{n}^{2+}}+2F{{e}^{2+}}\] \[2F{{e}^{3+}}+2{{e}^{-}}\xrightarrow{{}}2F{{e}^{2+}}\] According to Nemsts equation, \[{{E}_{cell}}\,=E_{cell}^{o}\,-\frac{RT}{nF}\,\ln \,\frac{{{[F{{e}^{2+}}]}^{2}}}{{{[F{{e}^{3+}}]}^{2}}}\] Thus, \[{{\text{E}}_{\text{cell}}}\] decreases as the \[[F{{e}^{2+}}]\] increases or \[[F{{e}^{3+}}]\] decreases.


You need to login to perform this action.
You will be redirected in 3 sec spinner