VMMC VMMC Medical Solved Paper-2006

  • question_answer
    \[{{C}_{6}}{{H}_{5}}-CH=CHCHO\xrightarrow{X}\]\[{{C}_{6}}{{H}_{5}}CH=CHC{{H}_{2}}OH\] In the above sequence X can be:

    A)  \[{{H}_{2}}/Ni\]

    B)                         \[NaB{{H}_{4}}\]            

    C)         \[{{K}_{2}}C{{r}_{2}}{{O}_{7}}/{{H}^{+}}\]  

    D)         both  and

    Correct Answer: B

    Solution :

    \[\text{NaB}{{\text{H}}_{\text{4}}}\]and \[\text{LiAl}{{\text{H}}_{\text{4}}}\]attacks only carbonyl group and reduce it into alcohol group. They do not attack on double bond. \[\underset{\text{Cinnamic}\,\text{aldehyde}}{\mathop{{{C}_{6}}{{H}_{5}}-CH=CHCHO}}\,\xrightarrow{\text{NaB}{{\text{H}}_{\text{4}}}}\] \[\underset{\text{Cinnamic}\,\text{alcohol}}{\mathop{{{C}_{6}}{{H}_{5}}=CH.C{{H}_{2}}OH}}\,\]


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