VMMC VMMC Medical Solved Paper-2004

  • question_answer
    Fats, on alkaline hydrolysis, gives

    A)  oils                                       

    B)  soaps  

    C)  detergents    

    D)  glycol + acid

    Correct Answer: C

    Solution :

    Fats are esters of higher fatty acids with glycerol, hence on alkaline hydrolysis, they give back glycerol and sodium or potassium salt of acid (this is called soap). \[\underset{\begin{smallmatrix}  C{{H}_{2}}OCOR \\  (fat) \end{smallmatrix}}{\mathop{\underset{|}{\mathop{\underset{\,\,\,\,\,\,CHOCOR\,+\,3NaOH\,\,\,\,\,\,\,\,\,\,\,\,\,\,\xrightarrow[{}]{{}}}{\mathop{\underset{|}{\mathop{C{{H}_{2}}OCOR}}\,}}\,}}\,}}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\] \[\underset{C{{H}_{2}}OH}{\mathop{\underset{|}{\mathop{\underset{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,CHOH+\,\underset{(soap)}{\mathop{3\,RCOONa}}\,}{\mathop{\underset{|}{\mathop{C{{H}_{2}}OH}}\,}}\,}}\,}}\,\]


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