VIT Engineering VIT Engineering Solved Paper-2015

  • question_answer
    Amongest\[\text{NO}_{\text{3}}^{\text{-}}\text{,AsO}_{\text{3}}^{\text{3-}}\text{,CO}_{\text{3}}^{\text{2-}}\text{,ClO}_{\text{3}}^{\text{-}}\text{,SO}_{\text{3}}^{\text{2-}}\] and \[BO_{3}^{3-},\]the non-planar species are

    A) \[CO_{3}^{2-},SO_{3}^{2-}\] and  \[BO_{3}^{2-}\]

    B) \[ASO_{3}^{3-},ClO_{3}^{-}\] and \[SO_{3}^{2-}\]

    C) \[NO_{3}^{-},CO_{3}^{2-}\] and \[BO_{3}^{3-}\]

    D) \[SO_{3}^{2-},NO_{3}^{-}\] and  \[BO_{3}^{3-}\]

    Correct Answer: B

    Solution :

    \[-nF{{E}^{\circ }}_{cell}=-RT\], \[{{E}^{\circ }}_{cell}=\frac{RT}{nF}\] and \[{{E}^{\circ }}_{cell}\] have \[=\frac{1}{2}\frac{RT}{F}\] hybridisation and hence are planar species while \[\begin{align}   & N{{H}_{4}}Cl\xrightarrow{\Delta }N{{H}_{3}}+HCl \\  & ABC \\ \end{align}\] and \[\begin{align}   & N{{H}_{3}}+HCl\to N{{H}_{4}}Cl \\  & \text{Bwhite fumes} \\ \end{align}\] have \[\begin{align}   & N{{H}_{3}}+2{{K}_{2}}\left[ Hg{{I}_{4}} \right]+3KOH\to  \\  & B\text{Nessler }\!\!'\!\!\text{ sreagent} \\ \end{align}\] hybridisation and hence are planar species


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