RAJASTHAN ­ PET Rajasthan PET Solved Paper-2009

  • question_answer
    The lowest\[p{{K}_{a}}\]value is for

    A)  phenol            

    B) \[m-\]cresol

    C)  o-cresol           

    D)  p-cresol

    Correct Answer: A

    Solution :

     [a] The value of\[p{{K}_{a}}\]is minimum for the strongest acid. In the given compound phenol is the strongest acid because in cresol electrons releasing group (ie,\[C{{H}_{3}}\])reduces the stability of phenoxide ion and therefore, acidic nature of cresol reduces. Hence, phenol has the lowest\[p{{K}_{a}}\]value (because maximum value of\[{{K}_{a}})\].


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