NEET Chemistry Equilibrium / साम्यावस्था NEET PYQ-Ionic Equilibrium

  • question_answer
    Which of the following salts will give highest pH in water?                                                    [AIPMT 2014]

    A)  \[KCl\]            

    B)                   \[NaCl\]           

    C)  \[N{{a}_{2}}C{{O}_{3}}\]

    D)       \[CuS{{O}_{4}}\]

    Correct Answer: C

    Solution :

           
    The highest pH refers to the basic solution containing \[O{{H}^{-}}\] ions. Therefore, the basic salt releasing \[O{{H}^{-}}\] ions on hydrolysis will give highest pH in water.
    Only the salt of strong base and weak acid would release \[O{{H}^{-}}\] ion on hydrolysis. Among the given sate, \[N{{a}_{2}}C{{O}_{3}}\] corresponds to the basic salt as it is formed by the neutralisation of \[NaOH\] [strong base] and \[{{H}_{2}}C{{O}_{3}}\] [weak acid].
    \[CO_{3}^{2-}+{{H}_{2}}O\rightleftharpoons HCO_{3}^{-}+O{{H}^{-}}\]


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