Manipal Medical Manipal Medical Solved Paper-2011

  • question_answer
    Catalyst\[SnC{{l}_{2}}/HCl\]is used in

    A)  Stephens reduction

    B)  Cannizzaros reaction

    C)  Clemmensen reduction

    D)  Rosenmunds reduction

    Correct Answer: A

    Solution :

     In the Stephens reduction alkyl cyanide is reduced to aldehyde by\[SnC{{l}_{2}}/HCl\]. \[R=C\equiv N+2H\xrightarrow[{}]{SnC{{l}_{2}}/HCl}\underset{alidime\text{ }hydrochloride}{\mathop{RCH=NH.HCl}}\,\] \[\xrightarrow[{}]{{{H}_{2}}O}\underset{aldehyde}{\mathop{RCHO}}\,+N{{H}_{4}}Cl\]


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