Manipal Engineering Manipal Engineering Solved Paper-2013

  • question_answer
    \[2C{{H}_{3}}\overset{\begin{smallmatrix}  O \\  || \end{smallmatrix}}{\mathop{C}}\,O{{C}_{2}}{{H}_{5}}\xrightarrow{{{C}_{2}}{{H}_{5}}ONa}A\], A is formed by Claisen condensation. Which is/are true about A?

    A) A forms oxime

    B) A shows tautomerism

    C) A shows iodoform test

    D) All of the above are true

    Correct Answer: D

    Solution :

    \[C{{H}_{3}}\overset{\begin{smallmatrix}  O \\  || \end{smallmatrix}}{\mathop{C}}\,O{{C}_{2}}{{H}_{5}}+HC{{H}_{2}}\overset{\begin{smallmatrix}  O \\  || \end{smallmatrix}}{\mathop{C}}\,O{{C}_{2}}{{H}_{5}}\] \[\xrightarrow{{{C}_{2}}{{H}_{5}}ONa}C{{H}_{3}}\overset{\begin{smallmatrix}  O \\  || \end{smallmatrix}}{\mathop{C}}\,\underset{(A)\,\,Keto\,\,ester}{\mathop{C{{H}_{2}}}}\,\overset{\begin{smallmatrix}  O \\  || \end{smallmatrix}}{\mathop{C}}\,O{{C}_{2}}{{H}_{5}}\] (b) A forms oxime due to keto group (c) A shows tautomerism (d)A shows iodoform test due to\[C{{H}_{3}}\overset{\begin{smallmatrix}  O \\  || \end{smallmatrix}}{\mathop{C}}\,-\]


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