JIPMER Jipmer Medical Solved Paper-2004

  • question_answer
    Which of the following has the maximum acidic strength?

    A)  p-nitrophenol

    B)  p-nitrobenzoic acid

    C)  o-nitrobenzoic acid

    D)  m-nitrobenzoic acid

    Correct Answer: C

    Solution :

    o-nitrobenzoic acid is the strongest acid among these. \[--N{{O}_{2}}\] group is a powerful electron withdrawing group and it has most effect when present at o-position. It is also known as o-effect. Due to its electron withdrawing nature electron density on H-atom in ?COOH group becomes very less, hence it can be easily donated.


You need to login to perform this action.
You will be redirected in 3 sec spinner