JIPMER Jipmer Medical Solved Paper-1998

  • question_answer
    The correct cell reaction for a cell, \[Fe|\,F{{e}^{2+}}(aq.,\,1.0\,m)|\,\,\,\,|\,C{{u}^{2+}}(aq.,\,1.0\,m|Cu)\]is:

    A)  \[Cu+F{{e}^{2+}}\xrightarrow{{}}C{{u}^{2+}}+Fe\]

    B)  \[2Cu+F{{e}^{2+}}\xrightarrow{{}}2C{{u}^{+}}+Fe\]

    C)  \[Fe+C{{u}^{2+}}\xrightarrow{{}}F{{e}^{2+}}+Cu\]

    D)  none of the above

    Correct Answer: C

    Solution :

    From the cell representation, it is clear that Fe makes the anode and Cu makes the cathode of cell. Hence, Fe will undergo oxidation while Cu reduction. Therefore, half-cell reactions will be \[Fe\xrightarrow{{}}F{{e}^{2+}}+2{{e}^{-}}\]                       ?(i)                 and        \[C{{u}^{2+}}+2{{e}^{-}}\xrightarrow{{}}Cu\]                      ?(ii) Hence, the cell reaction will be \[Fe+C{{u}^{2+}}\xrightarrow{{}}F{{e}^{2+}}+Cu\]


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