A) \[C{{H}_{3}}-\overset{O}{\mathop{\overset{||}{\mathop{C}}\,}}\,-O-\underset{O}{\mathop{\underset{||}{\mathop{S}}\,}}\,-Cl\]
B) \[C{{H}_{3}}-\overset{O}{\mathop{\overset{||}{\mathop{C}}\,}}\,-Cl\]
C) \[C{{H}_{3}}-\overset{O}{\mathop{\overset{||}{\mathop{C}}\,}}\,-OCl\]
D) \[ClC{{H}_{2}}-\overset{O}{\mathop{\overset{||}{\mathop{C}}\,}}\,-O-\overset{O}{\mathop{\overset{||}{\mathop{S}}\,}}\,-Cl\]
Correct Answer: B
Solution :
Acetyl chloride is formed when, acetic acid is heated with thionyl chloride. \[C{{H}_{3}}--\overset{O}{\mathop{\overset{||}{\mathop{C}}\,}}\,--OH+SOC{{l}_{2}}\xrightarrow[Pyridine]{\Delta }\] \[C{{H}_{3}}--\overset{O}{\mathop{\overset{||}{\mathop{C}}\,}}\,--Cl+S{{O}_{2}}+HCl\]
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