JAMIA MILLIA ISLAMIA Jamia Millia Islamia Solved Paper-2005

  • question_answer
        At what temperature is the rms velocity of a hydrogen molecule equal to that of an oxygen molecule at\[47{}^\circ C\]?

    A)  80 K                                      

    B)  \[-73\text{ }K\]

    C)  3 K                                        

    D)  20 K

    Correct Answer: D

    Solution :

                    The rms velocity of the molecule of a gas of molecular weight M at Kelvin temperature T is given by. \[{{C}_{rms}}=\sqrt{\left( \frac{3RT}{M} \right)}\] Let\[{{M}_{O}}\]and\[{{M}_{H}}\]are molecular weights of oxygen and hydrogen and\[{{T}_{O}}\]and\[{{T}_{H}}\]the corresponding Kelvin temperature at which \[{{C}_{rms}}\]is same for both gases.                 \[{{C}_{rms(O)}}={{C}_{rms(H)}}\]                 \[\sqrt{\left( \frac{3R{{T}_{O}}}{{{M}_{0}}} \right)}=\sqrt{\left( \frac{3R{{T}_{H}}}{{{M}_{H}}} \right)}\] Hence,  \[\frac{{{T}_{O}}}{{{M}_{0}}}=\frac{{{T}_{H}}}{{{M}_{H}}}\]                 \[{{T}_{O}}=273+48=320K\]                 \[{{M}_{O}}=32,{{M}_{H}}=2\] \[\therefore \]  \[{{T}_{H}}=\frac{2}{32}\times 320=20\,K\]


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