J & K CET Medical J & K - CET Medical Solved Paper-2009

  • question_answer
    The compound that does not undergo Hell-Volhard Zeiinsky reaction is

    A)  ethanoic acid   

    B)  propionic acid

    C)  Lso-butyric acid               

    D)  trichloroacetic acid

    Correct Answer: D

    Solution :

                    When carboxylic acids containing an\[\alpha -H\] atom are treated with\[C{{l}_{2}}/B{{r}_{2}}\]in the presence of red P,\[\alpha -\]halocarboxylic acids are obtained. The reaction is called Hell-Volhard-Zelinsky reaction. Here, it is also clear that this reaction is given by only those compounds that contain adeast one\[\alpha H\]atom. Hence, trichloroacetic acid\[(CC{{l}_{3}}COOH)\]due to the absence of\[\alpha H\]atom, does not give HVZ reaction.


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