J & K CET Medical J & K - CET Medical Solved Paper-2009

  • question_answer
    The IUPAC name of the molecule \[C{{H}_{3}}-\overset{\begin{smallmatrix}  O \\  || \end{smallmatrix}}{\mathop{C}}\,-\underset{\begin{smallmatrix}  | \\  C{{H}_{3}} \end{smallmatrix}}{\mathop{C}}\,=\underset{\begin{smallmatrix}  | \\  C{{H}_{3}} \end{smallmatrix}}{\mathop{C}}\,-\overset{\begin{smallmatrix}  O \\  || \end{smallmatrix}}{\mathop{C}}\,-OH\]

    A)  4-oxo-2, 3-dimethyl pent-2-en-l-oic acid

    B)  2-carboxy-3 methyl pent-2-en-3-one

    C)  4-carboxy-3 methyl pent-3-en-2-one

    D)  2, 3-dimethyM-oxo pent-2-en-l-oic-acid

    Correct Answer: D

    Solution :

                    The order of preference is\[COOH>>C=0\] Thus, \[\underset{2,\text{ }3-dimethyl-4-oxopent-2-en-1-oic\text{ }acid}{\mathop{\overset{5}{\mathop{C{{H}_{3}}}}\,-\overset{\begin{smallmatrix}  O \\  || \end{smallmatrix}}{\mathop{^{4}C}}\,-\underset{\begin{smallmatrix}  | \\  C{{H}_{3}} \end{smallmatrix}}{\mathop{\overset{3}{\mathop{C}}\,}}\,=\underset{\begin{smallmatrix}  | \\  C{{H}_{3}} \end{smallmatrix}}{\mathop{\overset{2}{\mathop{C}}\,}}\,-\overset{\begin{smallmatrix}  O \\  ||1 \end{smallmatrix}}{\mathop{^{4}C}}\,-OH}}\,\]


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