J & K CET Medical J & K - CET Medical Solved Paper-2009

  • question_answer
    Which one of the following has the highest Lewis acid strength?

    A) \[B{{I}_{3}}\]                                     

    B) \[BB{{r}_{3}}\]

    C) \[B{{F}_{3}}\]                                    

    D) \[BC{{l}_{3}}\]

    Correct Answer: A

    Solution :

                    Generally, higher the electronegativity, higher is the acidic strength. But in case of boron halides, back bonding takes place between B and F atoms, thus makes it less acidic. However such a back bonding does not take place between B and\[I,\]so\[B{{I}_{3}}\]has the highest Lewis acid strength among boron halides.


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