J & K CET Medical J & K - CET Medical Solved Paper-2008

  • question_answer
    Dehydration of alcohol is an example of which type of reaction?

    A)  Substitution    

    B)  Elimination

    C)  Addition                             

    D)  Rearrangement

    Correct Answer: B

    Solution :

                    Dehydration of alcohol involves the loss of two atoms or groups from the adjacent carbon atoms, hence it is an example of p-elimination reaction. \[\underset{ethanol}{\mathop{\overset{\beta }{\mathop{C{{H}_{3}}}}\,\overset{\alpha }{\mathop{C{{H}_{2}}OH}}\,}}\,\xrightarrow[{}]{+{{H}^{+}}}\overset{\beta }{\mathop{C{{H}_{3}}}}\,\overset{\alpha }{\mathop{C{{H}_{2}}}}\,\overset{+}{\mathop{O{{H}_{2}}}}\,\xrightarrow[-{{H}_{2}}O]{{}}\] \[\overset{\beta }{\mathop{C{{H}_{3}}}}\,\overset{\alpha }{\mathop{CH_{2}^{+}}}\,\xrightarrow[-{{H}^{+}}]{{}}\underset{ethene}{\mathop{\overset{\beta }{\mathop{C{{H}_{2}}}}\,}}\,=\overset{\alpha }{\mathop{C{{H}_{2}}}}\,\]


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