J & K CET Medical J & K - CET Medical Solved Paper-2006

  • question_answer
    The reaction conditions used for converting 1, 2-dibromopropane to propylene are:

    A)  KOH, alcohol\[/\Delta \]             

    B)  KOH, water\[/\Delta \]

    C)  Zn, alcohol \[/\Delta \]

    D)  Na, alcohol\[/\Delta \]

    Correct Answer: C

    Solution :

                    1, 2 dihalogen (vicinal) derivatives of the alkanes on reaction with zinc dust and methanol produces alkenes by loss of two halogen atoms (dehalogenation). \[\underset{1,\text{ }2-dibromopropane}{\mathop{C{{H}_{3}}-\underset{\begin{smallmatrix}  | \\  Br \end{smallmatrix}}{\mathop{CH}}\,-\underset{\begin{smallmatrix}  | \\  Br \end{smallmatrix}}{\mathop{CH}}\,}}\,+Zn\xrightarrow[{}]{alcohol/\Delta }\]\[\underset{propylene}{\mathop{C{{H}_{3}}CH=C{{H}_{2}}}}\,\]


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