J & K CET Medical J & K - CET Medical Solved Paper-2004

  • question_answer
    Volume of\[0.1\text{ }M\text{ }{{\text{K}}_{2}}C{{r}_{2}}{{O}_{7}}\] required to oxidize 35 mL of\[0.5\text{ }M\text{ }FeS{{O}_{4}}\]solution is:

    A)  29.2 mL                               

    B)  17.5 mL

    C)  175 mL                                

    D)  145 mL

    Correct Answer: A

    Solution :

                    \[C{{r}_{2}}O_{7}^{2-}+6F{{e}^{2+}}+14{{H}^{+}}\xrightarrow[{}]{{}}6F{{e}^{3+}}\] \[+2C{{r}^{3+}}+7{{H}_{2}}O\] Hence, 1 mol of\[C{{r}_{2}}O_{7}^{2-}=6\]mole of\[F{{e}^{2+}}\]                 \[\frac{{{M}_{1}}{{V}_{1}}}{1}=\frac{{{M}_{2}}{{V}_{2}}}{6}\]                 \[\frac{0.1\times {{V}_{1}}}{1}=\frac{0.5\times 35}{6}\]                 \[{{V}_{1}}=\frac{0.5\times 35}{6\times 0.1}\]                 \[{{V}_{1}}=29.2\,mL\]


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