J & K CET Medical J & K - CET Medical Solved Paper-2000

  • question_answer
    \[{{E}^{o}}\]value of\[M{{g}^{2+}}/Mg,F{{e}^{2+}}/Fe\]and \[Z{{n}^{2+}}/Zn\]are\[-2.37\text{ }V,-0.44\text{ }V\]and\[-\,0.76\text{ }V\] respectively. The correct statement is:

    A)  Mg oxidises Fe

    B)  Zn oxidises Fe

    C)  Zn reduces\[M{{g}^{2+}}\]

    D)  Zn reduces\[F{{e}^{2+}}\]

    Correct Answer: D

    Solution :

                    \[M{{g}^{2+}}+2{{e}^{-}}\xrightarrow{{}}Mg;\]  \[{{E}^{o}}=-2.37\,V\] \[Z{{n}^{2+}}+2{{e}^{-}}\xrightarrow{{}}Zn;\]     \[{{E}^{o}}=-\,0.76\,V\] \[F{{e}^{2+}}+2{{e}^{-}}\xrightarrow{{}}Fe;\]     \[{{E}^{o}}=-\,0.44\,V\] The reduction potential of\[Z{{n}^{2+}}/Zn\]is lower than\[F{{e}^{2+}}/Fe,\]hence, zinc can reduce\[F{{e}^{2+}}\]. \[Zn+F{{e}^{2+}}\xrightarrow{{}}Z{{n}^{2+}}+Fe\]


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