J & K CET Medical J & K - CET Medical Solved Paper-2000

  • question_answer
    Lindlars catalyst is:

    A) \[Pd\]and\[C{{O}_{2}}\]

    B) \[Pd\]and\[{{H}_{2}}\]

    C)  palladised charcoal deactivated with sulphur

    D)  \[Pd\]and\[CaC{{O}_{3}}\]

    Correct Answer: D

    Solution :

                    Lindlars catalyst is\[Pd-CaC{{O}_{3}}\]poisoned with lead acetate or quinoline. It is used for partial hydrogenation of alkynes. (i.e., =bond). \[R-C\equiv CH+{{H}_{2}}\xrightarrow[\begin{smallmatrix}  Poisoned\text{ }with\text{ }quinoline \\  \,\,\,\,\,\,or{{(C{{H}_{3}}COO)}_{2}}Pb \end{smallmatrix}]{Pd-CaC{{O}_{3}}}\]                                                 \[RCH=C{{H}_{2}}\]


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