EAMCET Medical EAMCET Medical Solved Paper-2006

  • question_answer
    The reaction,\[{{C}_{6}}{{H}_{5}}CHO+C{{H}_{3}}COO{{C}_{2}}{{H}_{5}}\xrightarrow{{}}\]\[{{C}_{6}}{{H}_{5}}CHO+CHCOO{{C}_{2}}{{H}_{5}}\]is called:

    A)  Benzoin condensation

    B)  claisen condensation

    C)  Cannizaros reaction

    D)  Perkin reaction

    Correct Answer: B

    Solution :

                     Claisen condensation: Aromatic aldehyde condenses with esters having \[\alpha -\] hydrogen atoms like ethyl acetate, in the presence of metallic Na and \[{{\text{C}}_{\text{2}}}{{\text{H}}_{\text{5}}}\text{OH}\] to form esters of \[\alpha ,\beta -\] unsaturated acids. \[\underset{\text{Benzaldehyde}}{\mathop{{{C}_{6}}{{H}_{5}}CHO}}\,\,+\underset{\text{Ethyl}\,\text{acetate}}{\mathop{\,HC{{H}_{2}}-COO{{C}_{2}}{{H}_{5}}}}\,\xrightarrow[{{C}_{2}}{{H}_{5}}OH]{Na}\] \[\underset{\text{Ethyl cinnamate}}{\mathop{{{C}_{6}}{{H}_{5}}CH=CHCOO{{C}_{2}}}}\,{{H}_{5}}+{{H}_{2}}O\]


You need to login to perform this action.
You will be redirected in 3 sec spinner