EAMCET Medical EAMCET Medical Solved Paper-2006

  • question_answer
    The bond angle in \[\text{As}{{\text{H}}_{\text{3}}}\]is greater than that in:

    A) \[N{{H}_{3}}\]                  

    B) \[{{H}_{2}}O\]

    C) \[BC{{l}_{3}}\]                  

    D) None of these

    Correct Answer: D

    Solution :

    \[\text{BC}{{\text{l}}_{\text{3}}}\] has bond angle equal to \[\text{12}{{\text{0}}^{o}}\] (trigonal planar). \[\text{N}{{\text{H}}_{\text{3}}}\] and \[{{\text{H}}_{\text{2}}}\text{O}\] have \[\text{s}{{\text{p}}^{3}}\] hybridization but due to the presence of lone pair of electrons, they have bond angle less than 1 \[{{109}^{o}}28\] \[(N{{H}_{3}}-{{107}^{o}},{{H}_{2}}O-{{104.5}^{o}}),\] \[\text{As}{{\text{H}}_{\text{3}}}\] (\[s{{p}^{3}}\] hybrid) has smaller bond angle than \[\text{N}{{\text{H}}_{\text{3}}}\] due to less electronegativity of As than N.


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