EAMCET Medical EAMCET Medical Solved Paper-2005

  • question_answer
    Which of the following reagents converts both acetaldehyde and acetone to alkanes?

    A)  \[Ni/{{H}_{2}}\]                              

    B)  \[LiAl{{H}_{4}}\]

    C)  \[{{I}_{2}}NaOH\]                          

    D)  \[Zn-Hg/conc.HCl\]

    Correct Answer: D

    Solution :

                     Clemmensens     reduction     (conc. \[\text{HCl/Zn}-\text{Hg}\]) or Wolf-Kishner reduction \[({{C}_{2}}{{H}_{5}}ONa/N{{H}_{2}}N{{H}_{2}})\] can be used to convert \[\text{C=O}\]group into \[\text{C}{{\text{H}}_{\text{2}}}\]group \[\underset{\begin{smallmatrix}  \text{Aldehyde}\,\text{or} \\  \text{ketone} \end{smallmatrix}}{\mathop{\begin{matrix}    R  \\    R  \\ \end{matrix}C=O}}\,\xrightarrow[conc.HCl]{Zn-Hg}\underset{hydrocarbon}{\mathop{\begin{matrix}    R  \\    R  \\ \end{matrix}C{{H}_{2}}}}\,\]


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