DUMET Medical DUMET Medical Solved Paper-2010

  • question_answer
    On adding excess of \[N{{H}_{4}}OH\] to copper sulphate solution,

    A)  a deep blue solution is obtained

    B)  a blue precipitate of \[Cu{{(OH)}_{2}}\] is obtained

    C)  a black precipitate of CuO is obtained

    D)  No change takes place

    Correct Answer: A

    Solution :

    \[CuS{{O}_{4}}+N{{H}_{4}}OH\xrightarrow{{}}\underset{cuprir\text{ }hydroxide}{\mathop{Cu{{(OH)}_{2}}}}\,\] \[Cu{{(OH)}_{2}}+N{{H}_{4}}OH\xrightarrow{{}}\] \[\underset{\begin{smallmatrix}  tetraamminecopper\text{ }\left( II \right)\text{ }sulphate \\  \left( deep\text{ }blue\text{ }solution \right) \end{smallmatrix}}{\mathop{[Cu{{(N{{H}_{3}})}_{4}}\,|\,S{{O}_{4}}}}\,\]


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