DUMET Medical DUMET Medical Solved Paper-2010

  • question_answer
    Calculate the wavelength of light required to break the bond between two chlorine atoms in a chlorine molecule. The Cl-Cl bond energy is 243kJ\[mo{{l}^{-1}}\]. (\[h=6.6\times {{10}^{-34}}J.\,s;c=3\times {{10}^{8}}m/s;\]; Avogadros number \[=6.02\times {{10}^{23}}mo{{l}^{-1}}\]).

    A)  \[8.18\times {{10}^{-31}}m\]   

    B)  \[6.26\times {{10}^{-21}}m\]

    C)  \[4.93\times {{10}^{-7}}m\]    

    D)  \[4.11\times {{10}^{-6}}m\]

    Correct Answer: C

    Solution :

    Given, Cl ? Cl bond energy = 243 kJ/mol \[=\frac{243\times {{10}^{3}}}{6.023\times {{10}^{23}}}J/atom\] \[E=\frac{hc}{\lambda }\] \[=\frac{243\times {{10}^{3}}}{6.023\times {{10}^{23}}}=\frac{6.6\times {{10}^{-34}}\times 3\times {{10}^{8}}}{\lambda }\] \[\lambda =\frac{6.6\times {{10}^{-34}}\times 3\times {{10}^{8}}\times 6.023\times {{10}^{23}}}{243\times {{10}^{3}}}\] \[=\frac{119.26\times {{10}^{-3}}}{243\times {{10}^{3}}}=4.907\times {{10}^{7}}m\] \[\approx 4.93\times {{10}^{-7}}m\]


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