DUMET Medical DUMET Medical Solved Paper-2008

  • question_answer
    An aqueous solution of \[CoC{{l}_{2}}\] on addition of excess of cone. \[HCl\] turns blue due to the formation of

    A)  \[[Co({{H}_{2}}O)]C{{l}_{2}}\]

    B)  \[[Co{{({{H}_{2}}O)}_{2}}]C{{l}_{4}}{{]}^{2-}}\]

    C)  \[{{[CoC{{l}_{4}}]}^{2-}}\]        

    D)  \[[Co{{({{H}_{2}}O)}_{2}}C{{l}_{2}}]\]

    Correct Answer: C

    Solution :

    \[CoC{{l}_{2}}\], a weak Lewis acid, reacts with chloride ion to produce salt containing the tetrahedral, \[{{[CoC{{l}_{4}}]}^{2-}}\] ion. It is blue when anhydrous and a deep magenta colour when hydrared, for this reason it is widely used as an indicator for water.


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