DUMET Medical DUMET Medical Solved Paper-2006

  • question_answer
    Bond energy of \[{{F}_{2}},C{{l}_{2}},B{{r}_{2}},{{I}_{2}}\] follows the order:

    A)  \[B{{r}_{2}}>{{F}_{2}}>C{{l}_{2}}>{{I}_{2}}\]

    B)  \[{{F}_{2}}>C{{l}_{2}}>B{{r}_{2}}>{{I}_{2}}\]

    C)  \[{{I}_{2}}>{{F}_{2}}>B{{r}_{2}}>C{{l}_{2}}\]

    D)  \[{{F}_{2}}>{{I}_{2}}>B{{r}_{2}}>C{{l}_{2}}\]

    Correct Answer: B

    Solution :

    Bond energy of \[{{F}_{2}},C{{l}_{2}},B{{r}_{2}}\] and \[{{I}_{2}}\] are as: \[F-F\xrightarrow{{}}150.6\,mo{{l}^{-1}}(kJ)\] \[Cl-Cl\xrightarrow{{}}242.7\,mo{{l}^{-1}}(kJ)\] \[Br-Br\xrightarrow{{}}188.3\,mo{{l}^{-1}}(kJ)\] \[I-I\xrightarrow{{}}150.6\,mo{{l}^{-1}}(kJ)\] Bond energy of \[{{F}_{2}}\] is lower because of repulsion between non bonded electrons of small sized F atom. So the order is \[{{F}_{2}}<C{{l}_{2}}>B{{r}_{2}}>{{I}_{2}}\]


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