DUMET Medical DUMET Medical Solved Paper-2006

  • question_answer
    Which of the following have pyramidal structure?

    A)  \[N{{H}_{3}}\]          

    B)  \[S{{F}_{4}}\]

    C)  \[B{{F}_{3}}\]

    D)  \[BC{{l}_{3}}\]

    Correct Answer: A

    Solution :

    Ammonia is a covalent molecule. Its structure is : \[H\,_{\bullet }^{\bullet }\overset{\begin{smallmatrix}  H \\  \,\bullet \,\,\bullet  \end{smallmatrix}}{\mathop{\underset{\begin{smallmatrix}  \bullet \,\,\bullet  \\  H \end{smallmatrix}}{\mathop{N}}\,\,_{\bullet }^{\bullet }}}\,\] or \[H-\overset{\begin{smallmatrix}  H \\  | \end{smallmatrix}}{\mathop{\underset{\begin{smallmatrix}  | \\  H \end{smallmatrix}}{\mathop{N}}\,\,_{\bullet }^{\bullet }}}\,\] According to M.O. theory, N has \[s{{p}^{3}}\]hybridisation since one pair of electrons on nitrogen remains free, the ammonia molecule gets distorted and acquires a pyramidal structure.


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