DUMET Medical DUMET Medical Solved Paper-2004

  • question_answer
    Bond order of \[{{O}_{2}}\] is:

    A)  2                

    B)  1.5

    C)  3              

    D)  3.5

    Correct Answer: A

    Solution :

    Key Idea: Bond order is calculated by using following formula after writing electronic configuration of molecule according to molecular orbital theory. \[{{O}_{2}}=8+8=16=\sigma 1{{s}^{2}},\overset{*}{\mathop{\sigma }}\,1{{s}^{2}},\sigma 2{{s}^{2}},\overset{*}{\mathop{\sigma }}\,2{{s}^{2}}\],\[\sigma 2p_{z}^{2},\pi 2p_{x}^{2},\pi 2p_{y}^{2},\overset{*}{\mathop{\pi }}\,2p_{x}^{1},\overset{*}{\mathop{\pi }}\,p_{y}^{1}\] Bond order \[=\frac{{{N}_{b}}-{{N}_{a}}}{2}\] Where, \[{{N}_{b}}=\] no. of electron in bonding molecular orbitals Na = no. of electron in antibonding molecular orbitals. Bond order \[=\frac{10-6}{2}=2\]


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