DUMET Medical DUMET Medical Solved Paper-2002

  • question_answer
    Which ethyl iodide and propyl iodide react with Na in the presence of ether, they form :

    A)  two alkanes    

    B)  four alkanes

    C)  three alkanes 

    D)  one alkane

    Correct Answer: C

    Solution :

    Key Idea: When different alkyl halides react with sodium in presence of ether, a mixture of alkanes is formed. \[C{{H}_{3}}C{{H}_{2}}Cl+Na+C{{H}_{3}}C{{H}_{2}}C{{H}_{2}}Cl\xrightarrow{Ether}\] \[\underset{butane}{\mathop{C{{H}_{3}}C{{H}_{2}}C{{H}_{2}}C{{H}_{3}}}}\,+\underset{pentane}{\mathop{C{{H}_{3}}C{{H}_{2}}C{{H}_{2}}C{{H}_{2}}C{{H}_{3}}}}\,\] \[+\underset{hexane}{\mathop{C{{H}_{3}}C{{H}_{2}}C{{H}_{2}}C{{H}_{2}}C{{H}_{2}}C{{H}_{3}}}}\,\] \[\therefore \] Three alkanes are formed.


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