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Chhattisgarh PMT Chhattisgarh PMT Solved Paper-2005

  • question_answer
    \[[Co{{(N{{H}_{3}})}_{4}}C{{l}_{2}}]N{{O}_{2}}\] and \[[Co{{(N{{H}_{3}})}_{4}}ClN{{O}_{2}}]Cl\]  are isomers of which type?

    A)  Geometrical     

    B)  Optical

    C)  Linkage                               

    D)  Ionization

    Correct Answer: D

    Solution :

    The given isomers have same molecular formula but furnish different ions in their aqueous solution. For example \[[Co{{(N{{H}_{3}})}_{4}}.C{{l}_{2}}]N{{O}_{2}}\xrightarrow{ionisation}\]                \[{{[Co{{(N{{H}_{3}})}_{4}}.C{{l}_{2}}]}^{+}}+NO_{2}^{-}\] \[[Co{{(N{{H}_{3}})}_{4}}Cl.N{{O}_{2}}]Cl\xrightarrow{ionisation}\]\[{{[CO{{(N{{H}_{3}})}_{4}}Cl.N{{O}_{2}}]}^{+}}+C{{l}^{-}}\]


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