CEE Kerala Engineering CEE Kerala Engineering Solved Paper-2000

  • question_answer
    Reduction of carbonyl compounds with hydrazine in presence of strong base is called:

    A)  Cannizaros reaction

    B)  Clemmensens reduction

    C)  Wolff-Kishner reduction

    D)  Meerwein-Pondorf reduction

    E)  Beckmann rearrangement

    Correct Answer: C

    Solution :

    Reduction of carbonyl compound with hydrazine in presence of strong base is called Wolff-Kishner reduction. In this reduction alkanes are formed. \[C{{H}_{3}}-\underset{\begin{smallmatrix}  | \\  H \end{smallmatrix}}{\mathop{C}}\,=O+{{H}_{2}}N.N{{H}_{2}}\xrightarrow[-{{H}_{2}}O]{{}}\] \[C{{H}_{3}}CH=N.N{{H}_{2}}\xrightarrow[glycol]{KOH,\,453-473\,K}\]                                                 \[C{{H}_{3}}.C{{H}_{3}}+{{N}_{2}}\]


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