CEE Kerala Engineering CEE Kerala Engineering Solved Paper-2000

  • question_answer
    An alkane\[{{C}_{7}}{{H}_{16}}\]is produced by the reaction of lithium dipentyl cuparate with ethyl bromide. The structural formula of the product is:

    A)  3-ethyl pentane

    B)         2-ethyl pentane

    C)  3-methyl hexane

    D)        2-methyl hexane

    E)  n-heptane

    Correct Answer: E

    Solution :

    When lithium dipentyl cuparate reacts with ethyl bromide, it will give n-heptane. This reaction is called Corey-House reaction. \[{{(C{{H}_{3}}C{{H}_{2}}C{{H}_{2}}C{{H}_{2}}C{{H}_{2}})}_{2}}CuLi+C{{H}_{3}}C{{H}_{2}}Br\] \[\xrightarrow[{}]{dryether}\underset{n-heptane}{\mathop{C{{H}_{3}}C{{H}_{2}}C{{H}_{2}}C{{H}_{2}}C{{H}_{2}}C{{H}_{2}}C{{H}_{3}}}}\,\] \[+C{{H}_{3}}C{{H}_{2}}Cu+LiBr\]


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