BHU PMT BHU PMT (Screening) Solved Paper-2011

  • question_answer
    \[[Co{{(N{{H}_{3}})}_{4}}C{{l}_{2}}]N{{O}_{2}}\]and\[[Co{{(N{{H}_{3}})}_{4}}Cl.N{{O}_{2}}]Cl\]are

    A)  optical                 

    B)  geometrical

    C)   ionisation        

    D)  linkage

    Correct Answer: C

    Solution :

                     \[[Co{{(N{{H}_{3}})}_{4}}C{{l}_{2}}]N{{O}_{2}}\]and\[[Co{{(N{{H}_{3}})}_{4}}Cl.N{{O}_{2}}]Cl\] are ionisation isomers because both produces different ions in solution state. \[[Co{{(N{{H}_{3}})}_{4}}Cl]N{{O}_{2}}{{[Co{{(N{{H}_{3}})}_{4}}C{{l}_{2}}]}^{+}}NO_{2}^{-}\] \[[Co{{(N{{H}_{3}})}_{4}}C{{l}_{2}}.N{{O}_{2}}]Cl{{[Co{{(N{{H}_{3}})}_{4}}Cl.N{{O}_{2}}]}^{+}}\] \[+C{{l}^{-}}\]


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