BHU PMT BHU PMT (Screening) Solved Paper-2011

  • question_answer
    Copper sulphate solution reacts with KCN to give

    A)  \[CuCN\]          

    B)  \[Cu{{(CN)}_{2}}\]

    C)  \[{{K}_{3}}[Cu{{(CN)}_{4}}]\]                    

    D)  \[{{K}_{2}}(Cu{{(CN)}_{4}}]\]

    Correct Answer: C

    Solution :

                     \[CuS{{O}_{4}}+2KCN\xrightarrow{{}}Cu{{(CN)}_{2}}+{{K}_{2}}S{{O}_{4}}\] \[2Cu{{(CN)}_{2}}\xrightarrow{{}}C{{u}_{2}}{{(CN)}_{2}}+{{(CN)}_{2}}\] \[C{{u}_{2}}{{(CN)}_{2}}+6KCN\xrightarrow{{}}2{{K}_{3}}[Cu{{(CN)}_{4}}]\]


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