BHU PMT BHU PMT (Screening) Solved Paper-2011

  • question_answer
    \[Ca{{C}_{2}}+{{H}_{2}}O\xrightarrow{{}}A\xrightarrow[{}]{{{H}_{2}}S{{O}_{4}}/HgS{{O}_{4}}}B\]Identify A and B in the given reaction

    A) \[{{C}_{2}}{{H}_{2}}\]and\[C{{H}_{3}}CHO\]

    B) \[C{{H}_{4}}\]and\[HCOOH\]

    C) \[{{C}_{2}}{{H}_{4}}\]and\[C{{H}_{3}}COOH\]

    D) \[{{C}_{2}}{{H}_{2}}\] and\[C{{H}_{3}}COOH\]

    Correct Answer: A

    Solution :

                     \[CaCa+2{{H}_{2}}\text{O}\xrightarrow{{}}\underset{(A)}{\mathop{Ca{{H}_{2}}}}\,+Ca{{(OH)}_{2}}\] \[\underset{\begin{smallmatrix}  CH \\  (A)  \\  acetylene \end{smallmatrix}}{\overset{CH}{\mathop{|||}}}\,\xrightarrow[{}]{Dil.\,{{H}_{2}}S{{O}_{4}}/HgS{{O}_{4}}}\underset{CHOH}{\overset{\,\,\,\,\,\,CH}{\mathop{||}}}\,\xrightarrow{{}}\]\[\underset{\begin{smallmatrix}  acetaldehyde \\  \,\,\,\,\,\,\,\,(B) \end{smallmatrix}}{\mathop{C{{H}_{3}}CHO}}\,\]


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