BHU PMT BHU PMT (Screening) Solved Paper-2009

  • question_answer
    Which one of the following is paramagnetic?

    A) \[{{O}_{2}}\]                                     

    B) \[{{N}_{2}}\]

    C)   \[He\]                                

    D) \[N{{H}_{3}}\]

    Correct Answer: A

    Solution :

                     The electronic configuration of\[{{O}_{2}}\]molecule is as: \[{{O}_{2}}:KK{{(\sigma 2s)}^{2}}{{(\overset{*}{\mathop{\sigma }}\,2s)}^{2}}{{(\sigma 2{{p}_{z}})}^{2}}{{(\pi 2{{p}_{x}})}^{2}}{{(\pi 2{{p}_{y}})}^{2}}\]                                                 \[{{(\overset{*}{\mathop{\pi }}\,2{{p}_{x}})}^{1}}{{(\overset{*}{\mathop{\pi }}\,2{{p}_{y}})}^{1}}\] In the\[{{O}_{2}}\]molecule there are two unpaired electrons, hence it shows paramagnetic character.


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