BHU PMT BHU PMT (Screening) Solved Paper-2008

  • question_answer
    Which of the following is incorrect?

    A)  A real gas behaves like an ideal gas over a wide range of pressure(\[\sim 100\]atm) at Boyle point.

    B)  A real gas behaves like an ideal gas over a wide range of pressure (\[\sim 100\]atm) at critical temperature of the gas.

    C) \[{{\left( \frac{\delta u}{\delta V} \right)}_{T}}=0\]for an ideal gas.

    D) \[{{\left( \frac{\delta u}{\delta V} \right)}_{T}}=\frac{a}{{{V}^{2}}}\]for a real gas obeying van der Waals' equation.

    Correct Answer: B

    Solution :

                     (i) At the Boyle temperature, the real gas behaves ideally over a wide range of pressure, because the effects of the size of molecules and intermolecular forces roughly compensate each other. (ii) A real gas behaves like an ideal gas over a wide range of pressure above critical temperature of gas


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