BHU PMT BHU PMT (Mains) Solved Paper-2010

  • question_answer

    Directions : In the following question more than one of the answers given may be correct. Select the correct answer and mark it according to the code:

    Aqueous solution of following compounds are electrolyzed. Acetylene gas is obtained from (1) sodium acetate          (2) sodium maleate (3) sodium succinate      (4) sodium fumarate

    A)  1, 2 and 3 are correct

    B)  1 and 2 are correct

    C)   2 and 4 are correct

    D)  1 and 3 are correct

    Correct Answer: C

    Solution :

                     \[\underset{sodium\text{ }maleate}{\mathop{\begin{matrix}    H-C-COONa  \\    ||  \\    H-C-COONa  \\ \end{matrix}}}\,\xrightarrow{Electrolysis}CH\equiv CH\] \[\underset{sodium\text{ }fumarate}{\mathop{\begin{matrix}    \,\,\,\,\,\,\,\,\,\,\,\,\,H-C-COONa  \\    ||  \\    NaOOC-C-H  \\ \end{matrix}}}\,\xrightarrow{Elecrolysis}CH\equiv CH\] Sodium acetate upon electrolysis gives methane while sodium succinate gives ethene (ethylene).


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