BHU PMT BHU PMT (Mains) Solved Paper-2008

  • question_answer
    Which of the following is not is structural with\[SiC{{l}_{4}}\]?

    A) \[SC{{l}_{4}}\]                                   

    B)  \[SO_{4}^{2-}\]

    C)   \[PO_{4}^{3-}\]                             

    D)  \[NH_{4}^{+}\]

    Correct Answer: A

    Solution :

                     The species having same number of bond pairs and lone pairs are isostructural. \[SiC{{l}_{4}}=(4bp+0lp)\Rightarrow \]tetrahedral structure \[SC{{l}_{4}}=(4bp+1lp)\Rightarrow \]see-saw like structure \[SO_{4}^{2-}(4bp+0lp)\Rightarrow \]tetrahedral structure \[PO_{4}^{3-}(4bp+0lp)\Rightarrow \]tetrahedral structure  \[NH_{4}^{+}(4bp+0lp)\Rightarrow \]tetrahedral structure Hence,\[SC{{l}_{4}}\]is not isostructural with\[SiC{{l}_{4}}\].


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