BCECE Medical BCECE Medical Solved Papers-2006

  • question_answer
    Addition of \[SnC{{l}_{2}}\] to \[HgC{{l}_{2}}\] gives precipitate :

    A)  white turning to red.

    B)  white turning to grey

    C)  black turning to white

    D)  none of the above

    Correct Answer: B

    Solution :

    Stannous chloride \[(SnC{{l}_{2}})\] is a good reducing agent. It reduces \[HgC{{l}_{2}}\] into Hg (grey precipitate), in two steps. \[SnC{{l}_{2}}+2HgC{{l}_{2}}\xrightarrow{{}}SnC{{l}_{4}}+\underset{white}{\mathop{HgC{{l}_{2}}\downarrow }}\,\] \[SnC{{l}_{2}}+HgC{{l}_{2}}\xrightarrow{{}}SnC{{l}_{4}}+\underset{grey}{\mathop{2Hg\downarrow }}\,\]


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