BCECE Engineering BCECE Engineering Solved Paper-2014

  • question_answer
    What is Z in the following reactions? \[\text{BC}{{\text{l}}_{\text{3}}}\text{+}{{\text{H}}_{\text{2}}}\xrightarrow[\text{45}{{\text{0}}^{\text{o}}}\text{-C}]{\text{Cu-Al}}\text{X+HCl}\] \[\text{X}\xrightarrow{\text{methylation}}Z\]

    A) \[(C{{H}_{3}})B{{H}_{2}}\]           

    B) \[(C{{H}_{3}}){{B}_{2}}{{H}_{2}}\]

    C) \[{{(C{{H}_{3}})}_{3}}{{B}_{2}}{{H}_{3}}\]             

    D) \[{{(C{{H}_{3}})}_{6}}{{B}_{2}}\]

    Correct Answer: B

    Solution :

    \[\text{BC}{{\text{l}}_{\text{3}}}\text{+}{{\text{H}}_{\text{2}}}\frac{\text{Cu-Al}}{\text{45}{{\text{0}}^{\text{o}}}\text{C}}\underset{\begin{smallmatrix}  \text{diborane} \\  X \end{smallmatrix}}{\mathop{{{\text{B}}_{\text{2}}}{{\text{H}}_{\text{6}}}}}\,\text{+HCl}\] \[\underset{X}{\mathop{{{\text{B}}_{\text{2}}}{{\text{H}}_{\text{6}}}}}\,\text{+4C}{{\text{H}}_{\text{3}}}\text{Cl}\xrightarrow{\text{Methylation}}\underset{Z}{\mathop{{{\text{(C}{{\text{H}}_{\text{3}}}\text{)}}_{\text{4}}}{{\text{B}}_{\text{2}}}{{\text{H}}_{\text{2}}}}}\,\]


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