NEET AIPMT SOLVED PAPER MAINS 2011

  • question_answer
    Consider the following processes
    \[\text{ }\!\!\Delta\!\!\text{ H}\,\text{(kJ/}\,\text{mol)}\]
    \[1/2A\to B\] + 150
    \[3B\to 2C+D\] - 125
    \[E+A\to 2D\] + 350
    For\[B+D\to E+2C,\Delta H\]will be

    A)  525 kJ/mol        

    B)  - 175 kJ/mol

    C)  -325 kJ/mol       

    D)  325 kJ/mol

    Correct Answer: B

    Solution :

    \[\frac{1}{2}A\xrightarrow[{}]{{}}B;\]      \[\Delta H=150\,kJ/mol\]             ?(i) \[3B\xrightarrow[{}]{{}}2C+D;\Delta H=-125\,kJ/mol\]    ?(ii) \[\underline{E+A\xrightarrow[{}]{{}}2D;\Delta H=+350\,kJ/mol}\]            ?(iii) By\[[2\times (i)+(ii)]-(iii),\]we have \[B+D\xrightarrow[{}]{{}}E+2C\] \[\therefore \]  \[\Delta H=150\times 2+(-125)-350\]                 \[=-175\,kJ/mol.\]


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