AIIMS AIIMS Solved Paper-2015

  • question_answer
    When a substance 'A' reacts with water, it produces a combustible gas 'B' and a solution of substance 'C' in water, while another substance 'H reacts with solution of 'C? to produce the same gas B on warming while 'D' can produce gas 'R on reaction with dilute\[\text{31}%\text{M}{{\text{g}}^{+}}+\text{69}%\text{M}{{\text{g}}^{\text{2}+}}\]at room temperature. 'A' imparts a deep golden yellow colour to a smokeless flame on Bunsen burner. Identify 'A', 'B', 'C" and 'D' respectively are

    A) \[C{{H}_{3}}CHO+N{{H}_{2}}.N{{H}_{2}}\to A\]

    B) \[\xrightarrow{B}C{{H}_{3}}C{{H}_{3}}+{{N}_{2}}\]

    C) \[C{{H}_{3}}CH=NN{{H}_{2}}\,and\,{{C}_{2}}{{H}_{5}}ONa\]

    D) \[\text{C}{{\text{H}}_{\text{3}}}\text{C}{{\text{H}}_{\text{2}}}\text{N}{{\text{H}}_{\text{2}}}\text{ and}\,{{\text{C}}_{\text{2}}}{{\text{H}}_{\text{5}}}\text{ONa}\]

    Correct Answer: B

    Solution :

    \[~\underset{A}{\mathop{\text{2Na}}}\,-\text{2}{{\text{H}}_{\text{2}}}\text{O}\to \underset{B}{\mathop{{{\text{H}}_{\text{2}}}}}\,+\underset{C}{\mathop{\text{2NaOH}}}\,\] \[\underset{D}{\mathop{Zn}}\,+\underset{C}{\mathop{2NaOH}}\,\xrightarrow{\Delta }N{{a}_{2}}Zn{{O}_{2}}+\underset{B}{\mathop{{{H}_{2}}}}\,\] \[\underset{D}{\mathop{Zn}}\,+{{H}_{2}}S{{O}_{4}}\xrightarrow{\Delta }ZnS{{O}_{4}}+\underset{B}{\mathop{{{H}_{2}}}}\,\] With Bunsen burner, Na gives golden yellow flame, K gives pink violet flame whereas Ca gives brick red colour.


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