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AIIMS AIIMS Solved Paper-2014

  • question_answer
    Assertion? Reaction of alcohols with \[SOC{{l}_{2}}\]is catalysed by the presence of a tertiary amine\[({{R}_{2}}N)\] Reason Tertiary amine promote the reaction by reacting with the by-product \[HCl\].

    A) Both Assertion and Reason are true and Reason is the correct explanation of Assertion

    B) Both Assertion and Reason are true and Reason is not the correct explanation of Assertion

    C) Assertion is true but Reason is false

    D) Both Assertion and Reason are false

    Correct Answer: A

    Solution :

                    \[ROH+SOC{{l}_{2}}\xrightarrow{{}}R-Cl+S{{O}_{2}}+HCl\] \[HCl+{{R}_{3}}N\xrightarrow{{}}{{R}_{3}}N.HCl\]


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